英语翻译In this paper,we report the crystal structure,spectralch
英语翻译
In this paper,we report the crystal structure,spectral
characterization and activity of mononuclear complex
Cu(EDTB)(NO3)2 1C2H5OH (I) in comparison with binuclear
Cu2(EDTB)(NO3)4 1 3H2O (II),as well as the
electrospray ionization mass spectrum (ESI-MS) of
catechol oxidation products.
The ligand N; N; N0; N0-tetrakis(20-benzimidazolyl
methyl)-1,2-ethanediamine (EDTB) and two complexes
were prepared as described before .The copper(II) ion is bound with four benzimidazolyl
(bzim) nitrogen atoms and two amino nitrogens
of the ligand,forming a distorted octahedron,which
consists of two benzimidazolyl nitrogens (N1 and N5)
and two amino nitrogens (N9 and N10) on an equatorial
plane,and the other two axial benzimidazolyl nitrogens.
In this paper,we report the crystal structure,spectral
characterization and activity of mononuclear complex
Cu(EDTB)(NO3)2 1C2H5OH (I) in comparison with binuclear
Cu2(EDTB)(NO3)4 1 3H2O (II),as well as the
electrospray ionization mass spectrum (ESI-MS) of
catechol oxidation products.
The ligand N; N; N0; N0-tetrakis(20-benzimidazolyl
methyl)-1,2-ethanediamine (EDTB) and two complexes
were prepared as described before .The copper(II) ion is bound with four benzimidazolyl
(bzim) nitrogen atoms and two amino nitrogens
of the ligand,forming a distorted octahedron,which
consists of two benzimidazolyl nitrogens (N1 and N5)
and two amino nitrogens (N9 and N10) on an equatorial
plane,and the other two axial benzimidazolyl nitrogens.
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本论文中,我们对比了多核Cu(EDTB)(NO3)2 1C2H5OH (I)、以及单核Cu2(EDTB)(NO3)4 1 3H2O (II)的晶体结构、光谱特征以及邻苯二酚氧化产物的ESI-MS.
EDTB和两个复合物的制备如前所述.铜（II）离子与四个苯并咪唑基氮原子束缚,两个氨基酸的连接氮原子,形成一个旋转的八面体,它由两个苯并咪唑氮原子（N1和N5的）和两个氨基氮原子（N9号和N10）构成一个平面,另两个轴由苯并咪唑氮原子组成.
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大概是这样,有些涉及到化学专业的不是很懂,楼主可以自己修改一下.
EDTB和两个复合物的制备如前所述.铜（II）离子与四个苯并咪唑基氮原子束缚,两个氨基酸的连接氮原子,形成一个旋转的八面体,它由两个苯并咪唑氮原子（N1和N5的）和两个氨基氮原子（N9号和N10）构成一个平面,另两个轴由苯并咪唑氮原子组成.
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大概是这样,有些涉及到化学专业的不是很懂,楼主可以自己修改一下.
1年前
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